Lecture · Stanford
Barriers and boundary conditions – David Miller
David Miller Quantum Mechanics Courses · David A. B. Miller
Stanford's David Miller shows why ψ and dψ/dz must both be continuous, then sends a wave at an infinitely thick barrier: inside, ψ falls off as e^(−κz) instead of stopping dead, and the barrier still reflects 100% but with a phase shift that has no classical analogue. His worked example is section 1's own: an electron of 1 eV meeting a 2 eV barrier, giving an amplitude decay length 1/κ of about 0.2 nm and a probability decay length of about 0.1 nm.